Antimony and the Macleay River

Antimony is a metal that is very well represented in our region. Many people have not heard of antimony as it is one of those elements that is ‘hidden away’ in many metal alloys and plastics and therefore often outshone by the more well known ones such as Iron, Nickel, Cobalt etc. It is a very important element for use in electronics and to modify the properties of rubber and plastics. It is even used in the cosmetics industry and HIV treatment medication (Wilson et al 2010). The main antimony mineral is called stibnite, an antimony sulphide mineral with the chemical formula Sb2S3, though there are many other less common antimony minerals.

The geographical distribution of antimony mineralisation in the Northern Rivers and New England closely follows certain geological units intruded by granite type plutons during the Permian (Ashley & Craw 2004). Essentially these deposits fall into the category of mesothermal mineral deposits meaning that they were formed through the action of hot fluids under pressure within the earth. The heat source is from regional heat increase due to the intrusion of many granites and sometimes from the actual contact zone of individual intrusions. The source of the fluids can be existing water in sedimentary rock pore space and/or derived from the breakdown of hydrous minerals such as clays. This hot water (often accompanied by elevated salts) can dissolve elements such as antimony as well as others such as gold and silver and then as they cool these elements are redeposited. In practice this tends to mean that the elements are located within veins of quartz or carbonate.

Probably the best known deposit of antimony is the Hillgrove Mine east of Armidale. The mine is in the headwaters of the Macleay River and was first mined for gold at the end of the nineteenth century. Indeed Hillgrove had a gold rush of such size that it was much bigger than Armidale (now its population is less than a hundred, I think). But many other areas have extensive mineralisation of antimony such as the area to the west of Bowraville in the headwaters of the Nambucca River catchment, areas north of Dorrigo in the headwaters of the Nymboida River catchment and even areas as far north as Tooloom which is to the north of Drake in the upper portions of the Clarence River catchment. Some of these deposits have been mined historically, though in the main gold has been the target and antimony just a by-product.

Antimony is an interesting element because it is chemically closely related to arsenic and therefore behaves in a similar way. This means it can also be dangerous in high concentrations and its environmental impact can be significant at even moderate to low levels, however, the nature of antimony has not been as extensively researched as arsenic and therefore the drinking water and environmental limits in Australia have been set lower than arsenic to increase the safety margin in assessing whether there is likely to be an adverse impact (Ashley et at 2004).

Interestingly, unlike many other elements that can be mobilised by the creation of sulphuric acid during the oxidation of the parent sulphide mineral, antimony tends not to remain in solution for long because the nature of the mineralisation model is such that carbonates are often present which neutralises the acids and leads to settling out of the antimony from the water column with iron and other metals. However, if the sediment is transported then this can be deposited a huge distance from its source and in some situations can be re-mobilized because of local stagnant water during dry periods combined with the presence of natural humic acids. This behaviour has been observed in the Macleay River catchment as suspended sediment from the areas around Hillgrove has been deposited on the flood plains as far away as Kempsey, very low concentrations of antimony are usually found in clear, clean water in the region. However, Wilson et al (2010) has shown that sometimes high antimony contents of alluvial soils can lead to uptake by flora and therefore this contaminant can then be accumulated in animals that graze on these plants.

References/bibliography:

*Ashley, P.M. & Craw, D. 2004. Structural controls on hydrothermal alteration and gold-antimony mineralisation in the Hillgrove area, NSW, Australia. Mineralium Deposita v39.
*Ashley, P.M., Craw, D., Graham, B.P. & Chappell, D.A. 2003. Environmental mobility of antimony around mesothermal stibnite deposits, New South Wales, Australia and southern New Zealand. Journal of Geochemical Exploration v77
*Craw, D, Wilson, N. & Ashley, P.M. 2004. Geochemical controls on the environmental mobility of Sb and As at mesothermal antimony and gold deposits. Applied Earth Science (Transactions of the International Mineralogy and Metallurgy Bulletin). v 113.
*Wilson, S.C., Lockwood, P.V., Ashley, P.M., & Tighe, M. 2010. The chemistry and behaviour of antimony in the soil environment with comparisons to arsenic: a critical review. Environmetnal Pollution v158.

How cold was it? Glaciers in New England?

I was very, very pleased to receive this comment by Bob (a physical geographer by ‘trade’) a bit more than a week ago. Bob posted the comment on my blog about Point Lookout and has been reproduced below:

"Rod,

You and your readers might be interested in a discovery made around Ebor and Guyra just last week, when I was working with a team of glacial buffs from UQ and UT. We found definite evidence of periglacial activity, presumably from the Last Glacial Maximum, ~20 000 years ago. The best examples were at Guyra on the slopes around Malpas Dam -- clear evidence of solifluction lobes, rock glaciers, snow hollows, and other freeze-thaw features, and what could only be described as incipient cirques -- ponds and bogs sapping back into the escarpment and probably still holding some snow in the frigid Guyra winters. The curious point is that they were between 1200 and 1300 metres, not at the highest points above 1500m where we were expecting them, but all on steep south facing escarpments.

One intriguing feature near Point Lookout, on the road up where it crosses the Little Styx River and at 1450m, was what looked very like a terminal moraine. This of course is a glacial, not a periglacial feature, so it is very hard to believe-but have a look at it, and see what you can make of it. There were at least 16 glacial cycles in the Pleistocene, so maybe one of them at least was really severe, and glaciated this far north. Otherwise, you have to go back to the Permian...

Bob H."


probable solifluction lobes and terraces on hill slope at Malpas Dam

This is exciting stuff to hear about because to my knowledge there is little or no evidence of cold climate landforms in the region. In fact I think the areas of the Tasmania are probably the only areas in Australia were these are frequent, though they have also been possibly identified in the Southern Alps and areas of Victoria. Certainly authors such as Petherick et al. (2011) and Hope (2005) did not identify such equivalent indicators of how far north such extreme cold could be detected. I understand that the cold climate landforms that Bob mentions have been found by researchers various universities such as from the University of Queensland, University of Technology, Sydney and the University of Tasmania. Acting on the tip off from Bob, I found an example of solifluction right on the northern side of Malpas Dam using Google Maps, this one is actually visible from the lookout on the southern side of the dam too (sorry about the quality of the photos, it was a long time since I took them and I didn’t realise what I was looking at that time). Get on Google maps and visit the dam yourself and have a look.


Same solifluction lobes visible south of the hill (same hill as picture above)

Solifluction is caused from the thawing of surface layers of permafrost during the summer leading to the thawed part of the soil profile slipping over the un-thawed permafrost and creating ‘lobes’ of soil. The cold climate structures that have been identified near Guyra are present on the southern side of the hill slopes where the sun was unable to melt much of the ice in the soil and therefore creates conditions of permafrost. Permafrost is not present anywhere on the Australian mainland today and demonstrates a significant change in climate has occurred (though those that know Guyra will still argue it is still uncomfortably cold there!).

What Bob appears to have found near point lookout is even more incredible, as a moraine is formed through the action of glaciers which are accumulations of ice on the surface that slowly moves through a landscape under the action of their own weight. Glaciers in Australia were thought to be limited to Tasmania and the Snowy Mountains. No doubt we will expect to see some published papers on the structure and context of these cold climate features in the region some time in the near future. I can't wait to read the published work that comes from this discovery. 

For further information on the individual cold climate features described above by Bob  visit the glossary, an online encyclopeadia or a good physical geography book such as Geosystems by Christopherson. If you are a little unclear about the locations of these sites and how they fit into a ‘Northern Rivers’ blog then it is worth mentioning this part of the New England, at Guyra and Malpas Dam are right at the head waters of the Gara River which is a tributary of the Macleay River that runs through Kempsey. The New England Highway in the Guyra area is pretty close to the actual crest of the catchments of the northern rivers, with the rivers to the west of it flowing into the Murray-Darling Basin and those to the east to the Pacific Ocean. Point Lookout is in the headwaters of the Bellinger River which runs trough Bellingen and is also part of the headwaters of the Macleay too.

References/Bibliography:

*Christopherson, R.W., 1997. Geosystems Wiley.
*Hope, P. 2005. The Weather and Climate of Australia During the Last Glacial Maximum. University of Melbourne, PhD Thesis, unpubl.
*Petherick, L.M., Moss, P.T & McGowan, H.A., 2011. Climatic and Environmental Variability During the Termination of the Last Glacial Stage in Coastal Eastern Australia: A Review. Australian Journal of Earth Science V.58.